Boiling Point Elevation Formula:
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Boiling point elevation is a colligative property that describes how the boiling point of a solvent increases when a non-volatile solute is added. The extent of boiling point elevation depends on the number of solute particles dissolved in the solvent.
The calculator uses the boiling point elevation formula:
Where:
Explanation: The van't Hoff factor accounts for the number of particles the solute dissociates into, while the ebullioscopic constant is specific to each solvent.
Details: Calculating boiling point elevation is essential in various applications including determining molecular weights of unknown compounds, preparing solutions with specific boiling points, and understanding colligative properties in physical chemistry.
Tips: Enter the pure solvent boiling point in °C, van't Hoff factor (typically 1 for non-electrolytes, 2 for NaCl-type electrolytes), ebullioscopic constant (0.512 °C·kg/mol for water), and molality in mol/kg. All values must be valid and non-negative.
Q1: What is the van't Hoff factor?
A: The van't Hoff factor (i) represents the number of particles a solute dissociates into in solution. For non-electrolytes, i = 1; for strong electrolytes like NaCl, i = 2.
Q2: What are common K_b values?
A: Water: 0.512 °C·kg/mol, Benzene: 2.53 °C·kg/mol, Ethanol: 1.22 °C·kg/mol, Acetic acid: 3.07 °C·kg/mol.
Q3: Why use molality instead of molarity?
A: Molality (moles per kg of solvent) is temperature-independent, making it more suitable for boiling point and freezing point calculations.
Q4: Does this work for all solutions?
A: The formula works best for dilute solutions. For concentrated solutions, deviations may occur due to non-ideal behavior.
Q5: Can I use this for mixed solvents?
A: The standard formula is designed for single solvents. Mixed solvents require more complex calculations.