Boiling Point Elevation Formula:
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Boiling point elevation is a colligative property that describes how the boiling point of a liquid increases when a non-volatile solute is added. It occurs because the solute particles lower the vapor pressure of the solvent, requiring a higher temperature to reach the boiling point.
The boiling point elevation formula:
Where:
Explanation: The van't Hoff factor accounts for the number of particles a solute dissociates into, the ebullioscopic constant is specific to each solvent, and molality represents the concentration of the solution.
Details: Understanding boiling point elevation is crucial in various applications including cooking, industrial processes, pharmaceutical formulations, and determining molecular weights of unknown compounds.
Tips: Enter the van't Hoff factor (typically 1 for non-electrolytes, higher for electrolytes), the solvent's ebullioscopic constant, and the molality of the solution. All values must be positive numbers.
Q1: What is the van't Hoff factor?
A: The van't Hoff factor (i) represents the number of particles a solute dissociates into in solution. For non-electrolytes, i=1; for electrolytes, it depends on the degree of dissociation.
Q2: How do I find the ebullioscopic constant for different solvents?
A: Ebullioscopic constants are tabulated values. For water, K_b = 0.512 °C kg/mol. Other solvents have different constants that can be found in chemistry reference tables.
Q3: Why use molality instead of molarity?
A: Molality is used because it is temperature-independent (based on mass), unlike molarity which is volume-based and changes with temperature.
Q4: Does boiling point elevation work for all solutions?
A: The formula works best for dilute solutions. For concentrated solutions, deviations may occur due to non-ideal behavior.
Q5: What are some practical applications?
A: Applications include calculating molecular weights, determining solute concentration, and in processes like sugar refining and antifreeze formulation.